Analytical solutions for sequentially coupled one-dimensional reactive transport problems – Part II: Special cases, implementation and testing

This is Part-II of a two-part article that presents analytical solutions to multi-species reactive transport equations coupled through sorption and sequential first-order reactions. In Part-I, we provide the mathematical derivations and in this article we discuss the computational techniques for implementing these solutions. We adopt these techniques to develop a general computer code and use it to verify the solutions. We also simplify the general solutions for various special-case transport scenarios involving zero initial condition, identical retardation factors and zero advection. In addition to this, we derive specialized solution expressions for zero dispersion and steady-state conditions. Whereever possible, we compare these special-case solutions against previously published analytical solutions to establish the validity of the new solution. Finally, we test the new solution against other published analytical and semi-analytical solutions using a set of example problems. 2007 Elsevier Ltd. All rights reserved.